| Yazarlar (4) |
Ferran Acuna-Pares
Liste, Amerika Birleşik Devletleri |
|
Miquel Costas
Liste, Güney Kore |
|
Josep M Luis
Liste, Güney Kore |
|
Julio Lloret-Fillol
Liste, Güney Kore |
| Özet |
| Recent studies have shown that non-heme iron complexes [Fe(LN4)X2], where LN4 stands for a tetradentate nitrogen based aminopyridine ligand (LN4 = Pytacn, mcp or mep, Pytacn = 1-(2-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane, mcp = N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)cyclohexane-trans-1,2-diamine, mep = N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethylendiamine), and X are monodentate ligands (X = Cl, CH3CN, CF3SO3--, or H2O), catalyze the oxidation of water using cerium(IV) ammonium nitrate (CAN) as oxidant. Spectroscopic monitoring of catalytic water oxidation with [Fe(CF3SO3)2(Pytacn)] established [FeIV(O)(OH2)(Pytacn)]2+ as an intermediate along the catalytic pathway, raising the question if these high valent species could be directly responsible for the O--O bond formation event. Herein, this question is addressed by a computational analysis of the thermodynamic and kinetic ... |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | Uluslararası alan indekslerindeki dergilerde yayınlanan tam makale |
| Dergi Adı | Inorganic Chemistry |
| Dergi Tarandığı Indeksler | |
| Makale Dili | İngilizce |
| Basım Tarihi | 06-2014 |
| Cilt No | 53 |
| Sayı | 11 |
| Sayfalar | 5474 / 5485 |
