Bonding Scheme Hydride Character and Magnetic Paths of HPO3 2 Versus SeO3 2 Building Units in Solids

Kovrugin, Vadim M.; Gordon, Elijah E.; KASAPBAŞI, EMİNE ESRA; Whangbo, Myung Hwan; Colmont, Marie; Siidra, Oleg I.; Colis, Silviu; Krivovichev, Sergey V.; Mentré, Olivier

doi:10.1021/acs.jpcc.5b10889

Bonding Scheme Hydride Character and Magnetic Paths of HPO3 2 Versus SeO3 2 Building Units in Solids

Yazarlar (9)
Vadim M. Kovrugin Université De Lille, Fransa
Elijah E. Gordon Nc State University, Amerika Birleşik Devletleri
Prof. Dr. Emine Esra KASAPBAŞI Kurum Bilgileri Sanat ve Tasarım Fakültesi Gastronomi ve Mutfak Sanatları Bölümü - Özgeçmiş Sayfası İletişim Bilgileri: İstanbul Aydın Üniversitesi, Türkiye
Myung Hwan Whangbo Nc State University, Amerika Birleşik Devletleri
Marie Colmont Université De Lille, Fransa
Oleg I. Siidra Saint Petersburg State University, Rusya Federasyonu
Silviu Colis Université De Strasbourg, Fransa
Sergey V. Krivovichev Saint Petersburg State University, Rusya Federasyonu
Olivier Mentré Université De Lille, Fransa

Devamını Göster

Özet

The abilities of the (HPO3)^2- and (SeO3)^2- anions as structure building units and as spin exchange paths between magnetic ions were investigated by preparing and analyzing the isostructural Fe2(SeO3)3 and Fe2(HPO3)3. In both compounds, the face-sharing Fe2O9 dimers are interconnected into chains by the (HPO3)^2- and (SeO3)^2- anions. The (HPO3)^2- is the structural counterpart of the Se electron lone pair of (SeO3)^2- due to the weak hydride character of the terminal hydrogen. However, they differ considerably as spin exchange paths between magnetic cations. Both compounds exhibit an effective magnetic dimer behavior, unexpectedly arising from the interdimer Fe - O···O - Fe exchange along the chain, but weaker in Fe2(HPO3)3 by a factor of ∼3. It is consistent with the general tendencies of the phosphite anions to act as a weak magnetic mediator, which is caused by the through-bond effect of the P³⁺ ion in the Fe - O···P³⁺···O - Fe exchange path, much weaker than in the selenite phase in absence of P³⁺d contribution. Reasons for stronger exchanges through phosphates or sulfates are also discussed.

Anahtar Kelimeler

Makale Türü	Özgün Makale
Makale Alt Türü	SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı	Journal of Physical Chemistry C
Dergi ISSN	1932-7447 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SSCI
Dergi Grubu	Q4
Makale Dili	İngilizce
Basım Tarihi	01-2016
Cilt No	120
Sayı	3
Sayfalar	1650 / 1656
DOI Numarası	10.1021/acs.jpcc.5b10889
Makale Linki	http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b10889

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
WoS	20
SCOPUS	19
Google Scholar	23

Bonding Scheme Hydride Character and Magnetic Paths of HPO3 2 Versus SeO3 2 Building Units in Solids

Dergi Adı	Journal of Physical Chemistry C
Yayıncı	American Chemical Society
Açık Erişim	Hayır
ISSN	1932-7447
E-ISSN	1932-7455
CiteScore	6,2
SJR	0,914
SNIP	0,801

Akademisyenler > Emine Esra KASAPBAŞI > Yayın Detayı

Bonding Scheme Hydride Character and Magnetic Paths of HPO3 2 Versus SeO3 2 Building Units in Solids

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